The problem is the noise floor of your PC Audio is not very low, as a result you are hearing the noise floor of your system in the output of your speakers.
LifeWire.Com has a good article on what Noise Floor is.
Our suggestion would be to use an audio interface that has a lower signal to noise ratio such as one of our USB Audio, 1394, or Thunderbolt interfaces that will lower the SNR for your monitors. However even the Studio Monitors will have their own SNR and depending on how high you have the amp cranked, you may hear the noise floor of the monitors when no audio is passing through it.